Synthesis of a new Ag supported on hydroxyapatite-core-shell-γ-Fe2O3 nanoparticles (γ-Fe2O3@HAp-Ag NPs) and its application as a Lewis acid catalyst in the preparation of β-azidoalcohols and β-thiocyanohydrins from epoxides

نویسندگان
حاجی بابایی لیلا ID 1
علایی توران ID 2
رجایی محمدصادق ID 3
عطارزاده روشا ID 4
مقتدایی فاطمه ID 5
آل غفور محمدتقی ID 6
علیزاده قاسم ID 7

1

2 دانشگاه آزاد اسلامی

3 دانشگاه یاسوج

4 دانشگاه آزاد اسلامی

5

6 دانشگاه باقرالعلوم

7 دانشگاه شیراز

doi
10.22034/AJGC/2020.1.4
چکیده

In this study, we synthesized Ag supported on hydroxyapatite-core-shell- γ -Fe 2 O 3 nanoparticles ( γ -Fe 2 O 3 @HAp-Ag NPs) as a new, lewis acid, and reusable heterogeneous nancatalyst. Then, it was successfully used for the synthesis of β -azido alcohols and β -thiocyanohydrins from the regioselective conversation of some epoxides by azide and thiocyanate anions in water. The reaction afforded the corresponding products with high regioselectivity under mild reaction conditions.

کلیدواژه‌ها
Ag supported, β-azido alcohols, Ring opening, Regioselective, Lewis acid