Cu(II)-Schiff base/SBA-15 as an efficient catalyst for synthesis of decahydroacridine-1,8-diones

نویسندگان

1 دانشگاه مراغه

2 دانشگاه تربیت مدرس

3 دانشگاه آزاد اسلامی

doi
10.22631/ajgc.2017.94130.1008
چکیده

Herein, we report a fast synthesis of 1,4-dihydropyridines, decahydroacridine-1,8-diones by one-pot multi-component reaction of 1,3-cyclohexanedione or dimidone, arylaldehydes, and ammonium acetate under solvent-less condition using Cu(II)-schiff base-SBA-15 as  a reusable heterogeneous catalyst in high yields. These kinds of catalysts are built from mesoporous silica SBA-15 which was covalently anchored with Cu(II) schiff base complex. The shorter reaction times, good yields, simple work-up procedure and environmentally friendly conditions are the main advantages of this method compared to the last one. This method is also  the first example of synthesizing acridines by Cu(II)-schiff base-SBA-15 as an efficient catalyst in solvent-free media which can be valuable to be used or investigated for similar systems. The product was identified by its 1 H NMR, mass and IR spectra, which were compared to those reported previously.