Synthesis and Characterization of Copper(II)-Oxide Nanoparticles from Two Cu(II) Coordination Polymers
نویسندگان
1
2 جهاد دانشگاهی
doi
چکیده
CuO nano particles were obtained by calcination of nano-sized [Cu(C 4 H 4 O 4 )(bipy)(H 2 O) 2 ].2H 2 O (1) and [Cu(2‚2′-bipy)](C 4 H 4 O 4 ) 0.5 (NO 3 )(H 2 O) (2) which are two Cu(II) coordination polymers. The two coordination polymers [Cu(C 4 H 4 O 4 )(bipy)(H 2 O) 2 ].2H 2 O and [Cu(2‚2′-bipy)](C 4 H 4 O 4 ) 0.5 (NO 3 )(H 2 O) were synthesized and characterized by Fourier transform infrared spectra (FT-IR spectroscopy), thermal gravimetric (TGA) and differential thermal analyses (DTA). CuO nano particles were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM).The two coordination polymers obtained possessed nano sizes.