Direct C-H difluoromethyl(thiol/selenol)ation of terminal alkynes: A review

نویسندگان
Didehban, Khadijeh ID 1
Niyazova, Aytan A. ID 2
Mirzoev, Garay S. ID 3
Allahverdiyeva, Ilhama F. ID 4

1 Payame Noor University, Tehran, Iran

2 Department of Engineering and Applied Sciences, Azerbaijan State University of Economics (UNEC), Baku, Azerbaijan

3 Department of Engineering and Applied Sciences, Azerbaijan State University of Economics (UNEC), Baku, Azerbaijan

4 Department of Engineering and Applied Sciences, Azerbaijan State University of Economics (UNEC), Baku, Azerbaijan

doi
10.22034/crl.2024.492011.1486
چکیده

The aim of the present review is to summarize the recent advances in the direct C-H difluoromethyl(chalcogen)ation of terminal alkynes. Hopefully, it can provide practical guidance for the readers who are interested in fluoroalkylation reactions. For simplicity and clarity, the review is divided into three sections: (i) difluoromethylation reactions; (ii) difluoromethylthiolation reactions; and (iii) difluoromethylselenolation reactions.

کلیدواژه‌ها
C-H functionalization, difluoromethylation, difluoromethylthiolation, difluoromethylselenolation, Alkynes