Recent advances in the synthesis of trifluoromethyl ethers through the direct O-trifluoromethylation of alcohols

نویسندگان
Niyazova, Aytan Aghaisa ID 1
Musayeva, V. H. ID 2
Razzaq, Hani Mueen ID 3
Rzayev, Rovnag ID 4
Huseynov, Movlud Arastun ID 5

1 Azerbaijan State University of Economics (UNEC), 6 Istiglaliyyat str., Baku AZ1001, Azerbaijan

2 Azerbaijan State University of Economics (UNEC), 6 Istiglaliyyat str., Baku AZ1001, Azerbaijan

3 Al-Zahrawi university college, Karbala , iraq

4 Composite Materials Scientific Research Center of Azerbaijan State University of Economics (UNEC), 194 M.Mukhtarov str. Baku, Azerbaijan

5 Azerbaijan State University of Economics (UNEC), 6 Istiglaliyyat str., Baku AZ1001, Azerbaijan

doi
10.22034/crl.2024.470142.1391
چکیده

Abstract: In this review, the pivotal achievements and recent advances on direct O- trifluoromethylation of alcohols reported up to 2024 are retrospectively considered and their potency for synthesis of useful trifluoromethyl ethers is demonstrated. The reported data are organized according to main types of catalytic systems (i.e., metal-catalyzed/mediated, electro-catalyzed, base-mediated, and catalyst-free O-trifluoromethylations).

کلیدواژه‌ها
organofluorine compounds, trifluoromethyl ethers, oxidative O-functionalization, trifluoromethylation, Alcohols