A chemoselective and green reduction of nitro arenes to aromatic amines with FeSO4, NaBH4, H3PW12O40 in water at room temperature
نویسندگان
1 Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.
2 Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.
3 Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.
4 Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.
5 Department of Chemistry, Islamic Azad University, Shahreza Branch,86145-311, Shahreza ,Isfahan , Iran.
doi
10.7508/jns.2011.01.004چکیده
A new efficient and practical method for the room-temperature reduction of aromatic nitro compounds employing FeSO4. 7H2O, NaBH4, H3PW12O40 system in H2O under mild conditions is reported. The method is simple, inexpensive, easily scaled-up and applicable for the large scale preparation of different substituted anilines.
