Preparation and Crystal Structure Determination of Zinc (II) Bromide Complexes at the Presence of Various Ligands
نویسندگان
1 Institute of Physic ASCR, v. v. i., Na Slovance 2, 182 21, Prague, Czech Republic
2 Institute of Physic ASCR, v. v. i., Na Slovance 2, 182 21, Prague, Czech Republic
3 Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran
4 Ph.D Educated, Department of Chemistry,Payamenoor University, Mashhad, Iran
5 Institute of Physic ASCR, v. v. i., Na Slovance 2, 182 21, Prague, Czech Republic
doi
10.33945/SAMI/CHEMM.2019.5.2چکیده
In this paper, we report the syntheses and crystal structuredetermination of three mononuclear and four-coordinated zinc(II) bromide complexes with chemical formula of [Zn(tsc)2]Br2 (1), Zn(PPh3)2Br2 (2) and Zn(Brcatsc)Br2 (3). The synthesized complexes are characterized by elemental analysis (CHN) and theircrystal structures are investigated by single crystal X-ray diffraction. In complex 1, the TSC coordinates to the zinc(II) ion as a bidentate ligand via N and S atoms. In complex 3, the thiosemicarbazone ligand Brcatsc coordinates to zinc(II) ion as a monodentate ligand via S atom. In these complexes, the zinc(II) ion coordinated in a distorted tetrahedral coordination geometry.
