An Efficient Method for the Nitration of Phenols with NaNO2 in the Presence of 3-Methyl-1-Sulfonic Acid Imidazolium Chloride

نویسندگان
Khazaei, A. ID 1
Zare, A. ID 2
Moosavi-Zare, A. R. ID 3
Zolfigol, M.A. ID 4

1 Department of Chemistry,Bu-Ali Sina University

2 Department of Chemistry,Northridge

3 Department of Chemistry,Berakly

4 Department of Chemistry,University of Bu-Ali-Sina

doi
چکیده

Nitrophenols can be obtained in high yields via nitrosation-oxidation of phenols by 3- methyl-1-sulfonic acid imidazolium chloride f[Msim]Clg as a new Brnsted acidic ionic liquid and NaNO2 at room temperature. In situ generation of HNO2 and a radical-cation mechanism via the nitrous acid catalyzed pathway appear to be applicable to phenol nitration using this reagent system.

کلیدواژه‌ها
3-Methyl-1-sulfonic acid imidazolium chloride f[Msim]Clg, Brnsted acidic ionic liquid, Nitrosation-oxidation, Nitration, Nitrophenols, Sodium nitrite (NaNO2