Lanthanide-based nano-porous coordination polymers (Ln=Tb, Dy, Er) and their application in the glycerol acetalization reaction
نویسندگان
1 Department of Inorganic Chemistry, Faculty of Chemistry, Alzahra University, Tehran, Iran.
2 Department of Inorganic Chemistry, Faculty of Chemistry, Alzahra University, Tehran, Iran.
3 Department of Inorganic Chemistry, Faculty of Chemistry, Alzahra University, Tehran, Iran.
doi
10.22036/j10.22036.2024.474691.1173چکیده
The acetalization of glycerol with acetone was investigated using a series of highly efficient and effective lanthanide-based nano-porous coordination polymers (Ln-based nano PCPs) as catalysts. The catalysts, namely Tb(BTC)(H2O).(DMF)1.1 (1), Dy(BTC)(H2O).(DMF)1.1 (2), and Er(BTC)(H2O).(DMF)1.1 (3), were based on BTC and Ln3+, and were optimized under varying reaction times, temperatures, catalyst/glycerol (Catal/Gly) molar ratios, and glycerol/acetone (Gly/Ace) molar ratios. The reusability of the catalysts was also thoroughly studied for this reaction.
