Use of Ultrasonic Pretreatment in the Reaction of Liquid Aerobic Oxidation of C11, C14 Paraffin Hydrocarbons in the Presence of (RCOO)3CR and (RCOO)2NI Catalysts
نویسندگان
1 Laser Technologies Research and Application Center (LATARUM), Kocaeli University, Yeniköy, Kocaeli 41275, TURKEY
2 Institute of Petrochemical Processes named Acad. Y.H. Mammadaliyev of MSE, Baku Az1025, AZERBAIJAN
3 Institute of Petrochemical Processes named Acad. Y.H. Mammadaliyev of MSE, Baku Az1025, AZERBAIJAN
4 Institute of Petrochemical Processes named Acad. Y.H. Mammadaliyev of MSE, Baku Az1025, AZERBAIJAN
5 Institute of Petrochemical Processes Named Acad. Y.H. Mammadaliyev of MSE, Baku Az1025, AZERBAIJAN
6 Institute of Petrochemical Processes Named Acad. Y.H. Mammadaliyev of MSE, Baku Az1025, AZERBAIJAN
7 Institute of Petrochemical Processes Named Acad. Y.H. Mammadaliyev of MSE, Baku Az1025, AZERBAIJAN
doi
10.30492/ijcce.2023.1971436.5685چکیده
The article discusses the outcomes of a liquid-phase aerobic oxidation study conducted on tetradecane and undecane, with the inclusion of chromium(III) and nickel(II) salts derived from natural petroleum acids that were pretreated using ultrasound. The research reveals that the induction period for n-alkane oxidation can be shortened by pretreating the catalyst with ultrasound. This effect is particularly noticeable with the chromium(III) catalyst, where ultrasonic pretreatment led to a two-fold reduction in reaction time and a substantial increase in product yield. Our findings suggest that employing ultrasonic pretreatment on catalysts holds significant potential for enhancing their performance in industrially important processes involving the oxidation of organic compounds.
