Keggin-Type Heteropolyacids-Catalyzed One Pot Oxidation-Trimerization of Alcohols into 2,4,6-Trisubstituted-1,3,5-Trioxanes

نویسندگان
Sadjadi, Sodeh ID 1
Hekmatshoar, Rahim ID 2
Heravi, M. Majid ID 3
Abdi Oskooie, Hossein ID 4
Bamoharram, Fatemeh ID 5

1 Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN

2 Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN

3 Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN

4 Department of Chemistry, School of Science, Alzahra University, Tehran, I.R. IRAN

5 Department of Chemistry, Islamic Azad University, Mashhad Branch, Mashhad, I.R. IRAN

doi
10.30492/ijcce.2009.13401
چکیده

 The catalytic air oxidation-trimerization of alcohols was carried out with hetropolyacids. In the presence of hetropolyacid formation of cyclotrimers of alcohols and aldol condensation products was observed. The 1,3,5-trioxanes were major and aldol condensation compounds were minor products.

کلیدواژه‌ها
Heteroplyacids, 1, 3, 5-Trioxanes, Alcohols, Oxidation, Trimerization, Aldol condensation