Methalloporphirins Catalyze Regio and Chemoselective Silylation of Hydroxy Groups with Hexamethyldisilazane (HMDS)

نویسندگان
Khayat, Zohreh ID 1
Tangestaninejad, Shahram ID 2
Firouzabadi, Habib ID 3
Sardarian, Ali Reza ID 4

1 Department of Chemistry, Faculty of Science, Shiraz University, Postcode 71454, Shiraz, I.R. IRAN

2 Department of Chemistry, Faculty of Science, Shiraz University, Postcode 71454, Shiraz, I.R. IRAN

3 Department of Chemistry, Faculty of Science, Shiraz University, Postcode 71454, Shiraz, I.R. IRAN

4 Department of Chemistry, Faculty of Science, Shiraz University, Postcode 71454, Shiraz, I.R. IRAN

doi
10.30492/ijcce.1996.10431
چکیده

Metalloporphirins; Cu(TPP), Mn(TPP)Cl, CO(TPP), Fe(TPP)Cl, zn(TPP) and Mn(OBP)Cl catalyze region and chemoselective silylation of hydroxyl groups with HMDS. Fe(TPP)Cl is the most effective catalyst and silylation occurs immediately in its presence at room temperature.

کلیدواژه‌ها
Metalloporphirin, Silylation, Catalysis, Hydroxy groups. Protection, Regio and Chemoselective, Hexamethyldisilazane