Synthesis and X-Ray Structural Determination of 2,4,6,8- Tetraphenyl- 2,4,6,8- Tetraazabicyclo [3.3.0] Octane

نویسندگان
Farnia, S. Morteza ID 1
Kakanejadifard, Ali ID 2
Todaro, Louis J. ID 3
Karimi, Sasan ID 4

1 Department of Chemistry, Faculty of Sciences, University of Tehran, Tehran, I.R. IRAN

2 Department of Chemistry, Faculty of Sciences,University of Tehran , Tehran, I.R. IRAN

3 Hoffmann-LaRoche Inc. Nutley, New Jersey 07110-1199, USA

4 Department of Chemistry, Hunter College, New York, New York, 10021, USA

doi
10.30492/ijcce.1993.10395
چکیده

Condensation of glyoxal, formaldehyde and anilines lead to the formation of 2,4,6,8- tetraphenyl and substituted phenyl 2,4,6,8-tetraazabicyclo [3.3.0] octanes. The reactions are sensitive to pH and temperature. Ortho derivatives of anilines do not participate in this condensation. X-ray structural determination reveals a cis-dienvelope geometery about the two fused rings.

کلیدواژه‌ها
Polyaza Polycyclic Derivative, 2, 4, 6, 8-Tetraphenyl-2, 8-Tetrazya Bicyclo [3.3.0] Octane-Cis Dienvelope Geometery, X-ray structural analysis